Construction of SnS2/TiO2 Heterojunction and Study of Its Photocatalytic Performance
DOI:
https://doi.org/10.62177/jaet.v2i4.907Keywords:
SnS2/TiO2 Composite, Photocatalysis, Hydrothermal Method, Methylene BlueAbstract
This thesis primarily prepared SnS2 and TiO2 monomers, and subsequently fabricated SnS2/TiO2 composites via a one-step hydrothermal method using tetrabutyl titanate, anhydrous ethanol, and concentrated nitric acid. The morphologies of the two prepared monomers and the SnS2/TiO2 composite were characterized using scanning electron microscopy (SEM). The photocatalytic performance was evaluated by degrading methylene blue solution under xenon lamp irradiation. The results demonstrate that the SnS2/TiO2 composite exhibits excellent photocatalytic activity, achieving a degradation rate as high as 92% for the methylene blue dye.
Downloads
References
Guo, C. B. (2021). Two-dimensional bismuth selenide anchored semiconductor catalyst and its photocatalytic performance [Doctoral dissertation]. Xiangtan University. https://doi.org/10.27426/d.cnki.gxtdu.2021.000555
Xu, B. X., & Yuan, F. (2011). Where is the water of life (pp. 8–9, 105–117). Beijing Yanshan Press.
Zhou, X. L. (2011). Chemistry and daily life (pp. 18–26). China Electric Power Press.
Wang, B., Zhang, X., Zhang, N., et al. (2015). Two-dimensional MoS₂ nanosheet-coated Bi₂S₃ discoids: Synthesis, formation mechanism, and photocatalytic application. Langmuir, 31(14), 4314–4322. https://doi.org/10.1021/acs.langmuir.5b00544
He, H. Y., Huang, J. F., Cao, L. Y., & Wu, J. P. (2007). Photocatalytic activity of mixture of SnS₂ and TiO₂ powders in destruction of methyl orange in water. Optoelectronic Advanced Materials, 12, 3781–3784. https://doi.org/10.1166/oam.2007.1452
Humayun, M., Raziq, F., Khan, A., et al. (2018). Modification strategies of TiO₂ for potential applications in photocatalysis: A critical review. Green Chemistry Letters and Reviews, 11(2), 86–102. https://doi.org/10.1080/17518253.2017.1366786
Zhang, Y. C., Du, Z. N., Li, S. Y., & Zhang, M. (2010). Novel synthesis and high visible light photocatalytic activity of SnS₂ nanoflakes from SnCl₂·2H₂O and S powders. Applied Catalysis B: Environmental, 95, 153–159. https://doi.org/10.1016/j.apcatb.2009.11.015
Akpan, U. G., & Hameed, B. H. (2009). Parameters affecting the photocatalytic degradation of dyes using TiO₂-based photocatalysts: A review. Journal of Hazardous Materials, 170, 520–529. https://doi.org/10.1016/j.jhazmat.2009.06.002
Zheng, L. X., et al. (2020). Photo/electro chemical applications of metal sulfide/TiO₂ heterostructures. Advanced Energy Materials, 10(1), 1902355. https://doi.org/10.1002/aenm.201902355
Kumair, et al. (2016). Efficiency enhancement in plasmonic dye-sensitized solar cells with TiO₂ photoanodes incorporating gold and silver nanoparticles. Journal of Applied Electrochemistry, 46(1), 47–58. https://doi.org/10.1007/s10800-015-0944-8
Wang, J., & Zhuan, R. (2020). Degradation of antibiotics by advanced oxidation processes: An overview. Science of the Total Environment, 701, 135023. https://doi.org/10.1016/j.scitotenv.2019.135023
Wei, Z., Liu, J., & Shangguan, W. (2020). A review on photocatalysis in antibiotic wastewater: Pollutant degradation and hydrogen production. Chinese Journal of Catalysis, 41(10), 1440–1455. https://doi.org/10.1016/S1872-2067(20)63698-8
Kovalakova, P., Cizmas, L., McDonald, T. J., et al. (2020). Occurrence and toxicity of antibiotics in the aquatic environment: A review. Chemosphere, 251, 126351. https://doi.org/10.1016/j.chemosphere.2020.126351
Martinez, J. L. (2009). Environmental pollution by antibiotics and by antibiotic resistance determinants. Environmental Pollution, 157(11), 2893–2902. https://doi.org/10.1016/j.envpol.2009.07.031
Yang, C., Wang, W., Shan, Z., & Huang, F. (2009). Preparation and photocatalytic activity of high-efficiency visible-light-responsive photocatalyst SnS₂/TiO₂. Solid State Chemistry, 182, 807–812. https://doi.org/10.1016/j.solidstatesciences.2009.02.016
Ismail, A. A., & Bahnemann, D. W. (2014). Photochemical splitting of water for hydrogen production by photocatalysis: A review. Solar Energy Materials and Solar Cells, 128, 85–101. https://doi.org/10.1016/j.solmat.2014.03.034
Wang, J., Wang, J., Wu, X., et al. (2017). Pt-TiO₂ microspheres with exposed {001} facets for degradation of formaldehyde in air: Formation mechanism and enhanced visible light photocatalytic activity. Materials Research Bulletin, 96, 262–269. https://doi.org/10.1016/j.materresbull.2017.08.031
Zhang, Y. C., Du, Z. N., Li, K. W., et al. (2011). Size-controlled hydrothermal synthesis of SnS₂ nanoparticles with high performance in visible light-driven photocatalytic degradation of aqueous methyl orange. Separation and Purification Technology, 81(1), 101–107. https://doi.org/10.1016/j.seppur.2011.06.018
Reli, M., Huo, P., Sihor, M., et al. (2016). Novel TiO₂/C₃N₄ photocatalysts for photocatalytic reduction of CO₂ and for photocatalytic decomposition of N₂O. Journal of Physical Chemistry A, 120(43), 8564–8573. https://doi.org/10.1021/acs.jpca.6b08444
Anucha, C. B., Altin, I., Bacaksiz, E., et al. (2022). Titanium dioxide (TiO₂)-based photocatalyst materials activity enhancement for contaminants of emerging concern (CECs) degradation: In the light of modification strategies. Chemical Engineering Journal Advances, 10, 100262. https://doi.org/10.1016/j.ceja.2022.100262
Downloads
How to Cite
Issue
Section
License
Copyright (c) 2025 Xiaofeng Zhang, Jinzhao Song

This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
DATE
Accepted: 2025-11-27
Published: 2025-12-18










